The Photovoltaic Performance of CdS/Cu2S (QD) Co-Sensitized Solar Cell

A. Khalid, K. Easawi, S. Abdallah, M. G. El-Shaarawy, S. Negm, H. Talaat

Abstract


The performance of CdS/Cu2S co-sensitized quantum dot solar cell (QDSSCs) is studied. CdS quantum dots (QDs) were adsorbed onto TiO2 using Successive Ionic Layer Adsorption and Reaction (SILAR) method for different cycles (2, 4, 6, 8 and 10). The Cu2S QDs were deposited onto TiO2/CdS10 cycle photoanodes using the same method. The FTO counter electrodes were coated with platinum, while the electrolyte containing polysulfide redox species was sandwiched between the two electrodes. The current density- voltage (J-V) characteristic curves of the assembled QDSSCs were measured at different cycles and AM 1.5 simulated sunlight. The value of current density (Jsc) and conversion efficiency (η) of TiO2/CdS/Cu2S are 252% larger than the TiO2/CdS values. The maximum values of Jsc and η are 3.56 mA/cm2 and 1.21% respectively corresponding to CdS10/Cu2S for 6 cycles of Cu2S.


Keywords


Quantum dot sensitized solar cell (QDSSCs); CdS QD; SILAR; photovoltaic parameters.

Full Text:

PDF

References


A.Badawi , N.Y. Mostafa , N.M. Al-Hosiny , A.Merazga , A.M. Albaradi , F. Abdel- Wahab and A. A. Atta. " The photovoltaic performance of Ag2 S quantum dots- sensitized solar cells using plasmonic Au nanoparticles/TiO2 working electrodes" Modern Physics Letters B, 1850172 (2018): 1-17.

S.K. Kokate, A.T. Supekar, P.K. Baviskar, B.M. Palve, S.R. Jadkar, K.C. Mohite, H.M. Pathan, "CdS sensitized pristine and Cd doped ZnO solar cells: Effect of SILAR cycles on optical properties and efficiency, Materials Science in Semiconductor Processing, 80 (2018)p. 179-183.

P.Yu, , et al., "Nanocrystalline TiO2 Solar Cells Sensitized with InAs Quantum Dots". J. Phys. Chem. B, 110(2006) p. 25451-25454.

N.Guijarro, et al., "CdSe Quantum Dot-Sensitized TiO2 Electrodes: Effect of Quantum Dot Coverage and Mode of Attachment". J. Phys. Chem. C,. 113(2009) p. 4208-4214.

J.H.Bang and P.V. Kamat, "Quantum Dot Sensitized Solar Cells. A Tale of Two Semiconductor Nanocrystals: CdSe and CdTe". ACS NANO, 3(2009) p. 1467–1476.

P.Sudhagar, et al., "The performance of coupled (CdS:CdSe) quantum dot-sensitized TiO2 nanofibrous solar cells". Electrochemistry Communications. 11(2009) p. 2220-2224.

K.Tvrdy , P.A. Frantsuzov, and P.V. Kamat, "Photoinduced electron transfer from semiconductor quantum dots to metal oxide nanoparticles". PNAS, 108(1)(2011) p. 29-34.

I.Barceló, T. Lana-Villarreal, and R. Gómez, "Efficient sensitization of ZnO nanoporous films with CdSe QDs grown by Successive Ionic Layer Adsorption and Reaction (SILAR) ". Journal of Photochemistry and Photobiology A: Chemistry, 220(1)(2011) p. 47-53.

A.Badawi , N.Al-Hosiny , S.Abdallah and H.Talaat, "Tuning photocurrent response through size control of CdSe quantum dots sensitized solar cell".Material Scince and Semicondactor Processing ,31 (2013)p. 6-13 .

N.Al-Hosiny , S.Abdallah , A.Badawi , K.Easawi and H.Talaat, "The photovoltaic performance o alloy CdTexS1-x quantum dot senstized solar cells " Material Scince and Semicondactor Processing ,26 (2014)p. 238-243. .

A.Badawi , N.Al-Hosiny , S.Abdallah , S.Negm and H.Talaat, "Tuning photocurrent response through size control of CdTe quantum dots sensitized solar cell". Solar energy ,88 (2013)p. 137-143 .

Kokate, Sunita K., Chaitali V. Jagtap, Prashant K. Baviskar, Sandesh R. Jadkar, Habib M. Pathan, and Kakasaheb C. Mohite. "CdS sensitized cadmium doped ZnO solar cell: Fabrication and characterizations" .Optik-International Journal for Light and Electron Optics 157 (2018): 628-634.

A.Badawi, N. Al-Hosiny, Amar Merazga, Ateyyah M. Albaradi, S. Abdallah, and H. Talaat. "Study of the back recombination processes of PbS quantum dots sensitized solar cells." Superlattices and Microstructures" 100 (2016).p 694-702.

Yang, Peizhi, Q.Tang, Chenming Ji, and H.Wang. "A strategy of combining SILAR with solvothermal process for In2S3 sensitized quantum dot-sensitized solar cells." Applied Surface Science.357 (2015)p. 666-671.

Y. Chen, Z. Qin, X. Wang, X. Guo, L. Guo, "Noble-metal-free Cu2S-modified photocatalysts for enhanced photocatalytic hydrogen production by forming nanoscale p–n junction structure" RSC Adv., 5 (2015) p.18159-18166.

A.Badawi, "Photoacoustic study of alloyed Cd1-xPbxS quantum dots sensitized solar cells electrodes"2016 DOI 10.1007/s10854-016-4781-1.2016.

G.Syrrokostas, M.Giannouli and P.Yianoulis. "effects of paste storage on the properties of nanostructured thin films for the development of dye-sensitized solar cell." Renewable Energy ,34 (2009)p.1759-1764.

A Hessein, A. Abd El-Moneim, "Synthesis of copper sulfide/reduced graphene oxide nanocomposites for use as the counter electrodes of high-performance CdS-sensitized solar cells", New Carbon Materials , 33(2018)p.26-35.

H.Thanh, Tung, D.Huynh Thanh, and V.Quang Lam. "The CdS/CdSe/ZnS photoanode cosensitized solar cells basedon Pt, CuS, Cu2S, and PbS counter electrodes." Advances in OptoElectronics" 9 (2014)p.23-37.

A. Badawi "Tunable energy band gap of Pb1-xCoxS quantum dots for optoelectronic application" Superlattices and Microstructures , https://doi.org/10.1016/j.spmi.2018.11.012.

A. Badawi, N. Al-Hosiny, S. Abdallah, "The photovoltaic performance of CdS quant dots sensitized solar cell using graphene/TiO2 working electrode", Superlattices and Microstructures 81 (2015) p.88–96.

Heba Hassan, T. Abdallah, S. Negm, and H. Talaat. "Rabi like angular splitting in Surface Plasmon Polariton–Exciton interaction in ATR configuration." Applied Surface Science " 441(2018).p. 341-346.

M. Nabil, K. Easawi, T. Abdallah, S. Abdallah, M. K. Elmancye, S. Negm, H.Talaat, "Performance Enhancement of TBAI Capped CdSeQuantum Dot Sensitized Solar Cells by an Interlayer Gold Nanoparticle", American Scientific Research Journal for Engineering, Technology and Science(ASRJETS) 53(2019)p. 27-42.

S. Abdallah, N. Al-Hosiny, A. Badawi, "Photoacoustic Study of CdS SemiconductorNanoparticles For Solar Cell Applications" Journal of Nanomaterial,1(2012)p.1-6.

S. Abdallah, N. Al-Hosiny, A. Badawi, "Photoacoustic Study of CdS SemiconductorNanoparticles For Solar Cell Applications" MSTI-Nanoteck,1(2012)p.55-60.

W.Li , X,Zhong "Capping Ligand-Induced Self-Assembly For Quantum Dot Sensitized Solar Cell ", Journal physical chemistry letters , 6(2015)p.796-806.

L.Tang, Y. Deng, G. Zeng, W. Hu, J.Wang, Y.Zhou, J. Wang, J. Tang , "CdS/Cu2S co-senstized TiO2 branched nanorod arroys of enchanced photoelectrochemical properties by forming nanoscale heterostructure "Journal of alloys and compound , 662(2016)p.516-527.

S.Abdallah " The Performance of Alloyed (CdS0.33Se10.67 ) Quantum Dots –Sensitized TiO2 solar cell "physics of semiconductor devices,48(2014)p.1385-1390.


Refbacks

  • There are currently no refbacks.


 
 
American Scientific Research Journal for Engineering,Technology,& Sciences
  
 

 

  

About ASRJETS | Privacy Policy | Terms & Conditions | Contact Us | Disclaimer| FAQs 

ASRJETS is published by (GSSRR).