Exhaust Flue Gas Concentration of Engines Running on Ethanol, Gasoline and Bio-oil - a Theoretical Estimate

  • Moilton Ribeiro Franco Júnior UFU – Federal University of Uberlandia – MG – Brazil
  • Nattácia Rodrigues de Araújo Felipe Rocha UniRV – Rio Verde University – Go – Brazil
  • Warley Augusto Pereira UniRV – Rio Verde University – Go – Brazil
Keywords: gaseous pollutants, concentration, reactions, temperature, pressure

Abstract

The creation of new technologies over the last 100 years has improved the quality of human life, but the necessary chemical and industrial transformations have caused significant changes in the environment. The production of new inputs depends on the chemical processes employed and, as a consequence, must be in line with water and air treatments that are undoubtedly undermined by world technological development. Thus, the principles of physics and chemistry apply to the prediction and understanding of the release of gaseous pollutants into the environment, which come from the burning of fuels in automobiles. It also discusses the influence of aspects related to the air content fed to the engine, as well as the effect of temperature and pressure on the concentration of these pollutants.

References

. E. Grosjean, R.A. Rasmussen and D. Grosjean. “Ambient levels of gas phase pollutants in Porto Alegre, Brazil”. Atmospheric Environment, vol. 32, issue 2025, pp. 3371-3379, Sep. 1998.

. P.C.Vasconcellos, L.R.F. Carvalho and C.S. Pool. “Volatile organic compounds inside urban tunnels of São Paulo city, Brazil”. Journal of the Brazilian Chemical Society, vol. 16, No 6A, pp. 1210-1216, 2005.

. J.P. Orlando, D.S. Alvim, A. Yamazaki, S.M. Corrêa and, L.V. Gatti. “Ozone precursors for the São Paulo metropolitan area”. Science of the Total Environment, vol. 408, issue 7, pp. 1612-1620, Mar. 2010.

. S.M. Corrêa, G. Arbilla, E.M. Martins, S.L. Quitério, C.S. Guimarães and L.V. Gatti. “Five-years of formaldehyde and acetaldehyde monitoring in the Rio de Janeiro downtown area – Brazil”. Atmospheric Environment, vol. 44, issue 19, pp. 2302-2308, Jun. 2010.

. L.F.A. Garcia, S.M. Corrêa, R. Penteado, L.C. Daemme, L.V. Gatti and D.S. Alvim. “Measurements of emissions from motorcycles and modeling its impact on air quality”. Journal of the Brazilian Chemical Society, vol. 24, No 3, pp. 375-384, 2013.

. Relatório Final - 1º Inventário nacional de emissões atmosféricas por veículos automotores rodoviários - janeiro de 2011 – Governo Dilma Roussef) (This publication was supported by the Instituto de Energia e Meio Ambiente (IEMA)) (in portuguese), 114p.

. D.J.O. Ferreira, J.H. Sosa Arnao, B.C. Moreira, L.P. Rangel and S.W. Park. “The impact of radiation in the gas combustion model for sugarcane bagasse grate boiler”. Brazilian Journal of Chemical Engineering, vol. 33, No 3, pp. 617-626, Jul. Sep. 2016.

. R.C.G. Oliveira, C.L. Cunha, S.M. Corrêa, A.R. Torres and E.R.A. Lima. “A simulation study about the impact of biodiesel use on the atmosphere of Rio de Janeiro city”. Brazilian Journal of Chemical Engineering, vol. 34, No 3, pp. 727-738, Jul.-Sep. 2017.

. G. Gonca. “Investigation of the influences of steam injection on the equilibrium combustion products and thermodynamic properties of biofuels (biodiesel and alcohols)”. Fuel, vol. 144, pp 244–258, Mar. 2015.

. R. Rodrigues, A.R. Muniz and N.R. Marcilio. “Evaluation of biomass and coal co–gasification of brazilian feedstock using a chemical equilibrium model”. Brazilian Journal of Chemical Engineering, vol. 33, No 2, pp. 401-414, Apr.-Jun. 2011.

. G. Kokkulunk, G. Gonca, V. Ayhan, I. Cesur and A. Parlak. “Theoretical and experimental investigation of diesel engine with steam injection system on performance and emission parameters”. Applied Thermal Engineering, vol. 54, issue 1, pp. 161-170, May 2013.

. I. Cesur, A. Parlak, A. Ayhan, B. Boru, G. Gonca. The effects of electronic controlled steam injection on spark ignition engine. Applied Thermal Engineering , vol. 55, issues 1-2, pp. 61-68, Jun. 2013.

. G. Gonca. “Investigation of the effects of steam injection on performance and NO emissions of a diesel engine running with ethanol–diesel blend”. Energy Convers Manage, vol. 77, pp. 450-457, Jan. 2014.

. G. Kokkulunk, G. Gonca and A. Parlak. The effects of design parameters on performance and no emissions of steam-injected diesel engine with exhaust gas recirculation. Arabian Journal for Science and Engineering vol. 39, pp. 4119-4129, Mar. 2014.

. G. Kokkulunk, A. Parlak, V. Ayhan, I. Cesur, G. Gonca and B. Boru. “Theoretical andexperimental investigation of steam injected diesel engine with EGR”. Energy, vol. 74, pp. 331-339, Sep. 2014.

. G. Gonca, B. Sahin, A. Parlak, Y. Ust, V. Ayhan, I. Cesur et al. “The effects of steam injection on the performance and emission parameters of a Miller cycle diesel engine”. Energy, vol. 78, pp. 266-275, Dec. 2014.

. M.W. Gery and R.R. Crouse. User’s guide for executing OZIPR. Boston – MA: U.S. Environmental Protection Agency, Atmospheric Sciences Research Laboratory, Jun. 1991, 3p.

. G.S. Tonnesen. User’s guide for executing OZIPR version 2.0. North Caroline: U.S. EPA, 2000.

. C.V. Souza, S.M. Corrêa, E.D. Sodré and J.R. Teixeira. “Volatile organic compound emissions from a landfill, plume dispersion and the tropospheric ozone modeling”. Journal of the Brazilian Chemical Society, vol. 23, No 3, pp. 496-504, Jan. 2012.

. F.S. Santos, G.A. Miranda, A.N.M. Carvalho, V.S.B. Carvalho and T.T.A. Albuquerque. “Regulated air pollutant emissions from higher emitters stationary sources in Belo Horizonte, Minas Gerais, Brazil”. Brazilian Journal of Chemical Engineering, vol. 36, No 2, pp. 775-784, Apr.-Jun. 2019.

. R. Piloto-Rodríguez, E. A. Melo, L. Goyos-Pérez, and S. Verhelst. “Conversion of by-products from the vegetable oil industry into biodiesel and its use in internal combustion engines: a review”. Brazilian Journal of Chemical Engineering, vol. 31, No 2, pp. 287-301, Apr.-Jun. 2014.

. A.A. Dantas Neto, M.R. Fernandes, E.L. Barros Neto, T.N.C. Dantas, and M.C.P.A. Moura. “Alternative fuels composed by blends of nonionic surfactant with diesel and water: engine performance and emissions”. Brazilian Journal of Chemical Engineering, Vol. 28, No 3, pp. 521-531, Jul.-Sep. 2011.

. Y. Fukuzawa, H. Shimoda, Y. Kakuhama, H. Endo, K. Tanaka. “Development of high efficiency miller cycle gas engine”. Mitsubishi Heavy Industries, Ltd. Technical Review, vol.38, No 3, Oct. 2001.

. K.B. Siddegowda and J. Venkatesh. “Performance and emission characteristics of MPFI engine by using gasoline – ethanol blends”. International Journal of Innovative Research in Science, Engineering and Technology, vol. 2, issue 9, pp. 4891-4897, Sep. 2013.

. J.C.V. Cevallos, “Ethanol fuel as renewal energy in spark ignition engines”. Master of Engineering Manufacturing Engineering and Management, 79 p., 2015.

. F.M.R. Mesquita, F.X. Feitosa, F.R. do Carmo, R.S. de Santiago-Aguia, and H.B. de Sant'Ana. “Viscosities and viscosity deviations of binary mixtures of biodiesel+petrodiesel (or n-hexadecane) at different temperatures”. Brazilian Journal of Chemical Engineering, vol. 29, No 3, pp. 653-664, Jul.-Sep. 2012.

. M. Baratieri, P. Baggio, L. Fiori and M. Grigiante. “Biomass as an energy source: Thermodynamic constraintson the performance of the conversion process”. Bioresource Technology, vol. 99, issue 15, pp. 7063-7073, Oct. 2008.

. R. Rodrigues, N.R. Marcilio, J.O. Trierweiler, M. Godinho and A.M.S. Pereira. “Co-gasification of footwear leather waste and high ash coal: a thermodynamic analysis”, in 27th Ann. Int. Pittsburgh Coal Conference Istanbul, Turkey, 2010, pp. 1-7.

. J. Belincanta, J.A. Alchorne, and M.T. da Silva. “The brazilian experience with ethanol Fuel: aspects of production, use, quality and distribution logistics”. Brazilian Journal of Chemical Engineering, vol. 33, No 4, pp. 1091-1102, Oct.-Dec. 2016.

. P. Atkins, J. de Paula. Físico-Química. Rio de Janeiro: LTC, vol. 1, 2008, pp. 512.

. A.K. Agarwal. “Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines”. Progress in Energy and Combustion Science, vol. 33, issue 3, pp. 233–271. Jun. 2007.

. R. Delgado and S. Paz. “Effect of different ethanol-gasoline blends on exhaust emissions and fuel consumption”, in SAE Technical Paper 2012-01-1273: SAE International, 2012.

. C. Sayin. “Engine performance and exhaust gas emissions of methanol and ethanol–diesel blends”. Fuel, vol. 89, issue 11, pp. 3410-3415, Nov. 2010.

. N.R. Abdullah, M.S.M. Zaharin, A.M.I. Mamat, M.R.M. Nawi, H. Sharudin. “Effects of ethanol blends on gasoline engine performance and exhaust emissions”. Jurnal Teknologi. Vol. 76, No 11, pp. 107-112, Jun. 2015.

. E. Esmaili, N. Mahinpey and C.J. Lim. “Modified equilibrium modelling of coal gasification with insitu CO2 capture using sorbent CaO: Assessment of approach temperature”. Chemical Engineering Research and Design, vol. 91, issue 7, pp. 1361-1369, Jul. 2013.

Published
2020-05-23
Section
Articles